<< Chapter < Page Chapter >> Page >

Explain what phosphorescence is and how it differs from fluorescence. Which process typically takes longer and why?

Got questions? Get instant answers now!

An electron is excited from the ground state of an atom (energy level 1) into a highly excited state (energy level 8). Which of the following electron behaviors represents the fluorescence effect by the atom?

  1. The electron remains at level 8 for a very long time, then transitions up to level 9.
  2. The electron transitions directly down from level 8 to level 1.
  3. The electron transitions from level 8 to level 1 and then returns quickly to level 8.
  4. The electron transitions from level 8 to level 6, then to level 5, then to level 3, then to level 1.

(d)

Got questions? Get instant answers now!

Describe the process of fluorescence in terms of the emission of photons as electron transitions between energy states. Specifically, explain how this process differs from ordinary atomic emission.

Got questions? Get instant answers now!

Section summary

  • An important atomic process is fluorescence, defined to be any process in which an atom or molecule is excited by absorbing a photon of a given energy and de-excited by emitting a photon of a lower energy.
  • Some states live much longer than others and are termed metastable.
  • Phosphorescence is the de-excitation of a metastable state.
  • Lasers produce coherent single-wavelength EM radiation by stimulated emission, in which a metastable state is stimulated to decay.
  • Lasing requires a population inversion, in which a majority of the atoms or molecules are in their metastable state.

Conceptual questions

How do the allowed orbits for electrons in atoms differ from the allowed orbits for planets around the sun? Explain how the correspondence principle applies here.

Got questions? Get instant answers now!

Atomic and molecular spectra are discrete. What does discrete mean, and how are discrete spectra related to the quantization of energy and electron orbits in atoms and molecules?

Got questions? Get instant answers now!

Hydrogen gas can only absorb EM radiation that has an energy corresponding to a transition in the atom, just as it can only emit these discrete energies. When a spectrum is taken of the solar corona, in which a broad range of EM wavelengths are passed through very hot hydrogen gas, the absorption spectrum shows all the features of the emission spectrum. But when such EM radiation passes through room-temperature hydrogen gas, only the Lyman series is absorbed. Explain the difference.

Got questions? Get instant answers now!

Lasers are used to burn and read CDs. Explain why a laser that emits blue light would be capable of burning and reading more information than one that emits infrared.

Got questions? Get instant answers now!

The coating on the inside of fluorescent light tubes absorbs ultraviolet light and subsequently emits visible light. An inventor claims that he is able to do the reverse process. Is the inventor’s claim possible?

Got questions? Get instant answers now!

What is the difference between fluorescence and phosphorescence?

Got questions? Get instant answers now!

How can you tell that a hologram is a true three-dimensional image and that those in 3-D movies are not?

Got questions? Get instant answers now!

Problem exercises

[link] shows the energy-level diagram for neon. (a) Verify that the energy of the photon emitted when neon goes from its metastable state to the one immediately below is equal to 1.96 eV. (b) Show that the wavelength of this radiation is 633 nm. (c) What wavelength is emitted when the neon makes a direct transition to its ground state?

(a) 1.96 eV

(b) ( 1240 eV·nm ) / ( 1 . 96 eV ) = 633 nm size 12{ \( "1240 eV·nm" \) / \( 1 "." "96 eV" \) =" 633 nm"} {}

(c) 60.0 nm

Got questions? Get instant answers now!

A helium-neon laser is pumped by electric discharge. What wavelength electromagnetic radiation would be needed to pump it? See [link] for energy-level information.

Got questions? Get instant answers now!

Ruby lasers have chromium atoms doped in an aluminum oxide crystal. The energy level diagram for chromium in a ruby is shown in [link] . What wavelength is emitted by a ruby laser?

The figure shows energy levels of chromium atoms in an aluminum oxide crystal. Ground state is at zero point zero electron volts, first metastable state is at one point seventy nine electron volts, second state is at two point three electron volts, and the third state is at three point zero electron volts.
Chromium atoms in an aluminum oxide crystal have these energy levels, one of which is metastable. This is the basis of a ruby laser. Visible light can pump the atom into an excited state above the metastable state to achieve a population inversion.

693 nm

Got questions? Get instant answers now!

(a) What energy photons can pump chromium atoms in a ruby laser from the ground state to its second and third excited states? (b) What are the wavelengths of these photons? Verify that they are in the visible part of the spectrum.

Got questions? Get instant answers now!

Some of the most powerful lasers are based on the energy levels of neodymium in solids, such as glass, as shown in [link] . (a) What average wavelength light can pump the neodymium into the levels above its metastable state? (b) Verify that the 1.17 eV transition produces 1 . 06 μm size 12{1 "." "06-μm"} {} radiation.

The figure shows different energy levels of neodymium atoms in glass. The ground state is at zero electron volts, first state is at zero point five zero electron volts, the metastable second state is at one point sixty seven electron volts, and the group state levels above metastable second are at two point one electron volts. The photons release one point seventeen electron volts at wavelength of one point zero six micro meters while coming from the metastable second state to first state.
Neodymium atoms in glass have these energy levels, one of which is metastable. The group of levels above the metastable state is convenient for achieving a population inversion, since photons of many different energies can be absorbed by atoms in the ground state.

(a) 590 nm

(b) ( 1240 eV·nm ) / ( 1 . 17 eV ) = 1.06 μm size 12{ \( "1240 eV·nm" \) / \( 1 "." "96 eV" \) =" 633 nm"} {}

Got questions? Get instant answers now!

Questions & Answers

what is defense mechanism
Chinaza Reply
what is defense mechanisms
Chinaza
I'm interested in biological psychology and cognitive psychology
Tanya Reply
what does preconceived mean
sammie Reply
physiological Psychology
Nwosu Reply
How can I develope my cognitive domain
Amanyire Reply
why is communication effective
Dakolo Reply
Communication is effective because it allows individuals to share ideas, thoughts, and information with others.
effective communication can lead to improved outcomes in various settings, including personal relationships, business environments, and educational settings. By communicating effectively, individuals can negotiate effectively, solve problems collaboratively, and work towards common goals.
it starts up serve and return practice/assessments.it helps find voice talking therapy also assessments through relaxed conversation.
miss
Every time someone flushes a toilet in the apartment building, the person begins to jumb back automatically after hearing the flush, before the water temperature changes. Identify the types of learning, if it is classical conditioning identify the NS, UCS, CS and CR. If it is operant conditioning, identify the type of consequence positive reinforcement, negative reinforcement or punishment
Wekolamo Reply
please i need answer
Wekolamo
because it helps many people around the world to understand how to interact with other people and understand them well, for example at work (job).
Manix Reply
Agreed 👍 There are many parts of our brains and behaviors, we really need to get to know. Blessings for everyone and happy Sunday!
ARC
A child is a member of community not society elucidate ?
JESSY Reply
Isn't practices worldwide, be it psychology, be it science. isn't much just a false belief of control over something the mind cannot truly comprehend?
Simon Reply
compare and contrast skinner's perspective on personality development on freud
namakula Reply
Skinner skipped the whole unconscious phenomenon and rather emphasized on classical conditioning
war
explain how nature and nurture affect the development and later the productivity of an individual.
Amesalu Reply
nature is an hereditary factor while nurture is an environmental factor which constitute an individual personality. so if an individual's parent has a deviant behavior and was also brought up in an deviant environment, observation of the behavior and the inborn trait we make the individual deviant.
Samuel
I am taking this course because I am hoping that I could somehow learn more about my chosen field of interest and due to the fact that being a PsyD really ignites my passion as an individual the more I hope to learn about developing and literally explore the complexity of my critical thinking skills
Zyryn Reply
good👍
Jonathan
and having a good philosophy of the world is like a sandwich and a peanut butter 👍
Jonathan
generally amnesi how long yrs memory loss
Kelu Reply
interpersonal relationships
Abdulfatai Reply
Got questions? Join the online conversation and get instant answers!
Jobilize.com Reply

Get Jobilize Job Search Mobile App in your pocket Now!

Get it on Google Play Download on the App Store Now




Source:  OpenStax, College physics for ap® courses. OpenStax CNX. Nov 04, 2016 Download for free at https://legacy.cnx.org/content/col11844/1.14
Google Play and the Google Play logo are trademarks of Google Inc.

Notification Switch

Would you like to follow the 'College physics for ap® courses' conversation and receive update notifications?

Ask