13.3 The ideal gas law

Learning objectives

By the end of this section, you will be able to:

• State the ideal gas law in terms of molecules and in terms of moles.
• Use the ideal gas law to calculate pressure change, temperature change, volume change, or the number of molecules or moles in a given volume.
• Use Avogadro’s number to convert between number of molecules and number of moles.

In this section, we continue to explore the thermal behavior of gases. In particular, we examine the characteristics of atoms and molecules that compose gases. (Most gases, for example nitrogen, ${\text{N}}_2$ , and oxygen, ${\text{O}}_2$ , are composed of two or more atoms. We will primarily use the term “molecule” in discussing a gas because the term can also be applied to monatomic gases, such as helium.)

Gases are easily compressed. We can see evidence of this in [link] , where you will note that gases have the largest coefficients of volume expansion. The large coefficients mean that gases expand and contract very rapidly with temperature changes. In addition, you will note that most gases expand at the same rate, or have the same $\beta$ . This raises the question as to why gases should all act in nearly the same way, when liquids and solids have widely varying expansion rates.

The answer lies in the large separation of atoms and molecules in gases, compared to their sizes, as illustrated in [link] . Because atoms and molecules have large separations, forces between them can be ignored, except when they collide with each other during collisions. The motion of atoms and molecules (at temperatures well above the boiling temperature) is fast, such that the gas occupies all of the accessible volume and the expansion of gases is rapid. In contrast, in liquids and solids, atoms and molecules are closer together and are quite sensitive to the forces between them.

To get some idea of how pressure, temperature, and volume of a gas are related to one another, consider what happens when you pump air into an initially deflated tire. The tire’s volume first increases in direct proportion to the amount of air injected, without much increase in the tire pressure. Once the tire has expanded to nearly its full size, the walls limit volume expansion. If we continue to pump air into it, the pressure increases. The pressure will further increase when the car is driven and the tires move. Most manufacturers specify optimal tire pressure for cold tires. (See [link] .)