<< Chapter < Page Chapter >> Page >

Section summary

  • The ideal gas law relates the pressure and volume of a gas to the number of gas molecules and the temperature of the gas.
  • The ideal gas law can be written in terms of the number of molecules of gas:
    PV = NkT , size 12{ ital "PV"= ital "NkT"} {}
    where P size 12{P} {} is pressure, V size 12{V} {} is volume, T size 12{T} {} is temperature, N size 12{N} {} is number of molecules, and k size 12{k} {} is the Boltzmann constant
    k = 1 . 38 × 10 23 J/K . size 12{k=1 "." "38" times "10" rSup { size 8{–"38"} } " J/K"} {}
  • A mole is the number of atoms in a 12-g sample of carbon-12.
  • The number of molecules in a mole is called Avogadro’s number N A size 12{N rSub { size 8{A} } } {} ,
    N A = 6 . 02 × 10 23 mol 1 . size 12{N rSub { size 8{A} } =6 "." "02" times "10" rSup { size 8{"23"} } `"mol" rSup { size 8{ - 1} } } {}
  • A mole of any substance has a mass in grams equal to its molecular weight, which can be determined from the periodic table of elements.
  • The ideal gas law can also be written and solved in terms of the number of moles of gas:
    PV = nRT , size 12{ ital "PV"= ital "nRT"} {}
    where n size 12{n} {} is number of moles and R size 12{R} {} is the universal gas constant,
    R = 8 . 31 J/mol K . size 12{R=8 "." "31"`"J/mol" cdot K} {}
  • The ideal gas law is generally valid at temperatures well above the boiling temperature.

Conceptual questions

Find out the human population of Earth. Is there a mole of people inhabiting Earth? If the average mass of a person is 60 kg, calculate the mass of a mole of people. How does the mass of a mole of people compare with the mass of Earth?

Under what circumstances would you expect a gas to behave significantly differently than predicted by the ideal gas law?

A constant-volume gas thermometer contains a fixed amount of gas. What property of the gas is measured to indicate its temperature?

Problems&Exercises

The gauge pressure in your car tires is 2 . 50 × 10 5 N/m 2 size 12{2 "." "50"´"10" rSup { size 8{5} } " N/m" rSup { size 8{2} } } {} at a temperature of 35 . 0 º C size 12{"35" "." 0°C} {} when you drive it onto a ferry boat to Alaska. What is their gauge pressure later, when their temperature has dropped to 40 . 0 º C size 12{ +- "40" "." 0°C} {} ?

1.62 atm

Convert an absolute pressure of 7 . 00 × 10 5 N/m 2 size 12{7 "." "00" times "10" rSup { size 8{5} } " N/m" rSup { size 8{2} } } {} to gauge pressure in lb/in 2 . size 12{"lb/in" rSup { size 8{2} } "." } {} (This value was stated to be just less than 90 . 0 lb/in 2 size 12{"90" "." "0 lb/in" rSup { size 8{2} } } {} in [link] . Is it?)

Suppose a gas-filled incandescent light bulb is manufactured so that the gas inside the bulb is at atmospheric pressure when the bulb has a temperature of 20 . 0 º C size 12{"20" "." 0°C} {} . (a) Find the gauge pressure inside such a bulb when it is hot, assuming its average temperature is 60 . 0 º C size 12{"60" "." 0°C} {} (an approximation) and neglecting any change in volume due to thermal expansion or gas leaks. (b) The actual final pressure for the light bulb will be less than calculated in part (a) because the glass bulb will expand. What will the actual final pressure be, taking this into account? Is this a negligible difference?

(a) 0.136 atm

(b) 0.135 atm. The difference between this value and the value from part (a) is negligible.

Large helium-filled balloons are used to lift scientific equipment to high altitudes. (a) What is the pressure inside such a balloon if it starts out at sea level with a temperature of 10 . 0 º C size 12{"10" "." 0°C} {} and rises to an altitude where its volume is twenty times the original volume and its temperature is 50 . 0 º C size 12{ +- "50" "." 0°C} {} ? (b) What is the gauge pressure? (Assume atmospheric pressure is constant.)

Confirm that the units of nRT size 12{ ital "nRT"} {} are those of energy for each value of R size 12{R} {} : (a) 8 . 31 J/mol K size 12{8 "." "31"" J/mol" cdot K} {} , (b) 1 . 99 cal/mol K size 12{1 "." "99 cal/mol" cdot K} {} , and (c) 0 . 0821 L atm/mol K size 12{0 "." "0821 L" cdot "atm/mol" cdot K} {} .

(a) nRT = ( mol ) ( J/mol K ) ( K ) = J size 12{ ital "nRT" = \( "mol" \) \( "J/mol" cdot K \) \( K \) =" J"} {}

(b) nRT = ( mol ) ( cal/mol K ) ( K ) = cal size 12{ ital "nRT" = \( "mol" \) \( "cal/mol" cdot K \) \( K \) =" cal"} {}

(c) nRT = ( mol ) ( L atm/mol K ) ( K ) = L atm = ( m 3 ) ( N/m 2 ) = N m = J

Questions & Answers

I'm interested in biological psychology and cognitive psychology
Tanya Reply
what does preconceived mean
sammie Reply
physiological Psychology
Nwosu Reply
How can I develope my cognitive domain
Amanyire Reply
why is communication effective
Dakolo Reply
Communication is effective because it allows individuals to share ideas, thoughts, and information with others.
effective communication can lead to improved outcomes in various settings, including personal relationships, business environments, and educational settings. By communicating effectively, individuals can negotiate effectively, solve problems collaboratively, and work towards common goals.
it starts up serve and return practice/assessments.it helps find voice talking therapy also assessments through relaxed conversation.
miss
Every time someone flushes a toilet in the apartment building, the person begins to jumb back automatically after hearing the flush, before the water temperature changes. Identify the types of learning, if it is classical conditioning identify the NS, UCS, CS and CR. If it is operant conditioning, identify the type of consequence positive reinforcement, negative reinforcement or punishment
Wekolamo Reply
please i need answer
Wekolamo
because it helps many people around the world to understand how to interact with other people and understand them well, for example at work (job).
Manix Reply
Agreed 👍 There are many parts of our brains and behaviors, we really need to get to know. Blessings for everyone and happy Sunday!
ARC
A child is a member of community not society elucidate ?
JESSY Reply
Isn't practices worldwide, be it psychology, be it science. isn't much just a false belief of control over something the mind cannot truly comprehend?
Simon Reply
compare and contrast skinner's perspective on personality development on freud
namakula Reply
Skinner skipped the whole unconscious phenomenon and rather emphasized on classical conditioning
war
explain how nature and nurture affect the development and later the productivity of an individual.
Amesalu Reply
nature is an hereditary factor while nurture is an environmental factor which constitute an individual personality. so if an individual's parent has a deviant behavior and was also brought up in an deviant environment, observation of the behavior and the inborn trait we make the individual deviant.
Samuel
I am taking this course because I am hoping that I could somehow learn more about my chosen field of interest and due to the fact that being a PsyD really ignites my passion as an individual the more I hope to learn about developing and literally explore the complexity of my critical thinking skills
Zyryn Reply
good👍
Jonathan
and having a good philosophy of the world is like a sandwich and a peanut butter 👍
Jonathan
generally amnesi how long yrs memory loss
Kelu Reply
interpersonal relationships
Abdulfatai Reply
What would be the best educational aid(s) for gifted kids/savants?
Heidi Reply
treat them normal, if they want help then give them. that will make everyone happy
Saurabh
Got questions? Join the online conversation and get instant answers!
Jobilize.com Reply
Practice Key Terms 4

Get Jobilize Job Search Mobile App in your pocket Now!

Get it on Google Play Download on the App Store Now




Source:  OpenStax, Concepts of physics with linear momentum. OpenStax CNX. Aug 11, 2016 Download for free at http://legacy.cnx.org/content/col11960/1.9
Google Play and the Google Play logo are trademarks of Google Inc.

Notification Switch

Would you like to follow the 'Concepts of physics with linear momentum' conversation and receive update notifications?

Ask