6.4 X rays: atomic origins and applications

Each type of atom (or element) has its own characteristic electromagnetic spectrum. X rays lie at the high-frequency end of an atom’s spectrum and are characteristic of the atom as well. In this section, we explore characteristic x rays and some of their important applications.

We have previously discussed x rays as a part of the electromagnetic spectrum in Photon Energies and the Electromagnetic Spectrum . That module illustrated how an x-ray tube (a specialized CRT) produces x rays. Electrons emitted from a hot filament are accelerated with a high voltage, gaining significant kinetic energy and striking the anode.

There are two processes by which x rays are produced in the anode of an x-ray tube. In one process, the deceleration of electrons produces x rays, and these x rays are called bremsstrahlung , or braking radiation. The second process is atomic in nature and produces characteristic x rays , so called because they are characteristic of the anode material. The x-ray spectrum in [link] is typical of what is produced by an x-ray tube, showing a broad curve of bremsstrahlung radiation with characteristic x-ray peaks on it.

The spectrum in [link] is collected over a period of time in which many electrons strike the anode, with a variety of possible outcomes for each hit. The broad range of x-ray energies in the bremsstrahlung radiation indicates that an incident electron’s energy is not usually converted entirely into photon energy. The highest-energy x ray produced is one for which all of the electron’s energy was converted to photon energy. Thus the accelerating voltage and the maximum x-ray energy are related by conservation of energy. Electric potential energy is converted to kinetic energy and then to photon energy, so that $E_{\text{max}}={\text{hf}}_{\text{max}}=q_{e}V\text{.}$ Units of electron volts are convenient. For example, a 100-kV accelerating voltage produces x-ray photons with a maximum energy of 100 keV.

Some electrons excite atoms in the anode. Part of the energy that they deposit by collision with an atom results in one or more of the atom’s inner electrons being knocked into a higher orbit or the atom being ionized. When the anode’s atoms de-excite, they emit characteristic electromagnetic radiation. The most energetic of these are produced when an inner-shell vacancy is filled—that is, when an $n=1$ or $n=2$ shell electron has been excited to a higher level, and another electron falls into the vacant spot. A characteristic x ray (see Photon Energies and the Electromagnetic Spectrum ) is electromagnetic (EM) radiation emitted by an atom when an inner-shell vacancy is filled. [link] shows a representative energy-level diagram that illustrates the labeling of characteristic x rays. X rays created when an electron falls into an $n=1$ shell vacancy are called $K_{\alpha }$ when they come from the next higher level; that is, an $n=2$ to $n=1$ transition. The labels $\mathrm{K,\; L,\; M,...}$ come from the older alphabetical labeling of shells starting with $K$ rather than using the principal quantum numbers 1, 2, 3, …. A more energetic $K_{\beta }$ x ray is produced when an electron falls into an $n=1$ shell vacancy from the $n=3$ shell; that is, an $n=3$ to $n=1$ transition. Similarly, when an electron falls into the $n=2$ shell from the $n=3$ shell, an $L_{\alpha }$ x ray is created. The energies of these x rays depend on the energies of electron states in the particular atom and, thus, are characteristic of that element: every element has it own set of x-ray energies. This property can be used to identify elements, for example, to find trace (small) amounts of an element in an environmental or biological sample.