14.3 Resistance and resistivity  (Page 2/6)

Temperature variation of resistance

The resistivity of all materials depends on temperature. Some even become superconductors (zero resistivity) at very low temperatures. (See [link] .) Conversely, the resistivity of conductors increases with increasing temperature. Since the atoms vibrate more rapidly and over larger distances at higher temperatures, the electrons moving through a metal make more collisions, effectively making the resistivity higher. Over relatively small temperature changes (about $\text{100º}\text{C}$ or less), resistivity $\rho$ varies with temperature change $\mathrm{\Delta }T$ as expressed in the following equation

where ${\rho }_0$ is the original resistivity and $\alpha$ is the temperature coefficient of resistivity    . (See the values of $\alpha$ in [link] below.) For larger temperature changes, $\alpha$ may vary or a nonlinear equation may be needed to find $\rho$ . Note that $\alpha$ is positive for metals, meaning their resistivity increases with temperature. Some alloys have been developed specifically to have a small temperature dependence. Manganin (which is made of copper, manganese and nickel), for example, has $\alpha$ close to zero (to three digits on the scale in [link] ), and so its resistivity varies only slightly with temperature. This is useful for making a temperature-independent resistance standard, for example.

Note also that $\alpha$ is negative for the semiconductors listed in [link] , meaning that their resistivity decreases with increasing temperature. They become better conductors at higher temperature, because increased thermal agitation increases the number of free charges available to carry current. This property of decreasing $\rho$ with temperature is also related to the type and amount of impurities present in the semiconductors.