10.9 The electromagnetic spectrum  (Page 9/32)

The tanning response is a defense mechanism in which the body produces pigments to absorb future exposures in inert skin layers above living cells. Basically UV-B radiation excites DNA molecules, distorting the DNA helix, leading to mutations and the possible formation of cancerous cells.

Repeated exposure to UV-B may also lead to the formation of cataracts in the eyes—a cause of blindness among people living in the equatorial belt where medical treatment is limited. Cataracts, clouding in the eye’s lens and a loss of vision, are age related; 60% of those between the ages of 65 and 74 will develop cataracts. However, treatment is easy and successful, as one replaces the lens of the eye with a plastic lens. Prevention is important. Eye protection from UV is more effective with plastic sunglasses than those made of glass.

A major acute effect of extreme UV exposure is the suppression of the immune system, both locally and throughout the body.

Low-intensity ultraviolet is used to sterilize haircutting implements, implying that the energy associated with ultraviolet is deposited in a manner different from lower-frequency electromagnetic waves. (Actually this is true for all electromagnetic waves with frequencies greater than visible light.)

Flash photography is generally not allowed of precious artworks and colored prints because the UV radiation from the flash can cause photo-degradation in the artworks. Often artworks will have an extra-thick layer of glass in front of them, which is especially designed to absorb UV radiation.

Uv light and the ozone layer

If all of the Sun’s ultraviolet radiation reached the Earth’s surface, there would be extremely grave effects on the biosphere from the severe cell damage it causes. However, the layer of ozone ( ${\text{O}}_3$ ) in our upper atmosphere (10 to 50 km above the Earth) protects life by absorbing most of the dangerous UV radiation.

Unfortunately, today we are observing a depletion in ozone concentrations in the upper atmosphere. This depletion has led to the formation of an “ozone hole” in the upper atmosphere. The hole is more centered over the southern hemisphere, and changes with the seasons, being largest in the spring. This depletion is attributed to the breakdown of ozone molecules by refrigerant gases called chlorofluorocarbons (CFCs).

The UV radiation helps dissociate the CFC’s, releasing highly reactive chlorine (Cl) atoms, which catalyze the destruction of the ozone layer. For example, the reaction of ${\text{CFCl}}_3$ with a photon of light $\left(\text{hv}\right)$ can be written as:

The Cl atom then catalyzes the breakdown of ozone as follows:

A single chlorine atom could destroy ozone molecules for up to two years before being transported down to the surface. The CFCs are relatively stable and will contribute to ozone depletion for years to come. CFCs are found in refrigerants, air conditioning systems, foams, and aerosols.

International concern over this problem led to the establishment of the “Montreal Protocol” agreement (1987) to phase out CFC production in most countries. However, developing-country participation is needed if worldwide production and elimination of CFCs is to be achieved. Probably the largest contributor to CFC emissions today is India. But the protocol seems to be working, as there are signs of an ozone recovery. (See [link] .)