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Calculate the amount of energy produced by the fission of 1.00 kg of , given the average fission reaction of produces 200 MeV.
Strategy
The total energy produced is the number of atoms times the given energy per fission. We should therefore find the number of atoms in 1.00 kg.
Solution
The number of atoms in 1.00 kg is Avogadro’s number times the number of moles. One mole of has a mass of 235.04 g; thus, there are . The number of atoms is therefore,
So the total energy released is
Discussion
This is another impressively large amount of energy, equivalent to about 14,000 barrels of crude oil or 600,000 gallons of gasoline. But, it is only one-fourth the energy produced by the fusion of a kilogram mixture of deuterium and tritium as seen in the previous section. Even though each fission reaction yields about ten times the energy of a fusion reaction, the energy per kilogram of fission fuel is less, because there are far fewer moles per kilogram of the heavy nuclides. Fission fuel is also much more scarce than fusion fuel, and less than 1% of uranium is readily usable.
One nuclide already mentioned is , which has a 24,120-y half-life and does not exist in nature. Plutonium-239 is manufactured from in reactors, and it provides an opportunity to utilize the other 99% of natural uranium as an energy source. The following reaction sequence, called breeding , produces . Breeding begins with neutron capture by :
Uranium-239 then decays:
Neptunium-239 also decays:
Plutonium-239 builds up in reactor fuel at a rate that depends on the probability of neutron capture by (all reactor fuel contains more than ). Reactors designed specifically to make plutonium are called breeder reactors . They seem to be inherently more hazardous than conventional reactors, but it remains unknown whether their hazards can be made economically acceptable. The four reactors at Chernobyl, including the one that was destroyed, were built to breed plutonium and produce electricity. These reactors had a design that was significantly different from the pressurized water reactor illustrated above.
Plutonium-239 has advantages over as a reactor fuel — it produces more neutrons per fission on average, and it is easier for a thermal neutron to cause it to fission. It is also chemically different from uranium, so it is inherently easier to separate from uranium ore. This means has a particularly small critical mass, an advantage for nuclear weapons.
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