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Write the chemical formula for copper (II) chloride.
A molecule of copper (II) chloride contains the elements copper and chlorine .
The valency of copper is 2, while the valency of chlorine is 1. In a molecule of copper (II) chloride, two atoms of chlorine will combine with one atom of copper.
The chemical formula for copper (II) chloride is therefore:
The overall charge of an ionic compound will always be zero and so the negative and positive charge must be the same size. We can use this information to work out what the chemical formula of an ionic compound is if we know the charge on the individual ions. In the case of for example, the charge on the sodium is and the charge on the chlorine is . The charges balance ( ) and therefore the ionic compound is neutral. In , magnesium has a charge of and oxygen has a charge of . Again, the charges balance and the compound is neutral. Positive ions are called cations and negative ions are called anions .
Some ions are made up of groups of atoms, and these are called compound ions . It is a good idea to learn the compound ions that are shown in [link]
Name of compound ion | formula | Name of compound ion | formula |
Carbonate | Nitrate | ||
Sulphate | Hydrogen sulphite | ||
Hydroxide | Hydrogen sulphate | ||
Ammonium | Dihydrogen phosphate | ||
Nitrate | Hypochlorite | ||
Hydrogen carbonate | Acetate (ethanoate) | ||
Phosphate | Oxalate | ||
Chlorate | Oxide | ||
Cyanide | Peroxide | ||
Chromate | Sulphide | ||
Permanganate | Sulphite | ||
Thiosulphate | Manganate | ||
Phosphide | Hydrogen phosphate |
In the case of ionic compounds, the valency of an ion is the same as its charge (Note: valency is always expressed as a positive number e.g. valency of the chloride ion is 1 and not -1). Since an ionic compound is always neutral , the positive charges in the compound must balance out the negative. The following are some examples:
Write the chemical formula for potassium iodide.
Potassium iodide contains potassium and iodide ions.
Potassium iodide contains the ions ( ; ) and ( ; ). In order to balance the charge in a single molecule, one atom of potassium will be needed for every one atom of iodine.
The chemical formula for potassium iodide is therefore:
Write the chemical formula for sodium sulphate.
Sodium sulphate contains sodium ions and sulphate ions.
(valency = 1; charge = +1) and ( ; ).
Two sodium ions will be needed to balance the charge of the sulphate ion. The chemical formula for sodium sulphate is therefore:
Write the chemical formula for calcium hydroxide.
Calcium hydroxide contains calcium ions and hydroxide ions.
Calcium hydroxide contains the ions ( ) and ( ). In order to balance the charge in a single molecule, two hydroxide ions will be needed for every ion of calcium.
The chemical formula for calcium hydroxide is therefore:
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